Taming Liquid Crystal Self-Assembly: The Multifaceted Response of Nematic and Smectic Shells to Polymerization.
نویسندگان
چکیده
By photopolymerizing liquid crystal shells, their rich variety of self-assembled structures can be rendered permanent and the lifetime extended from days to months, without removing the characteristic responsiveness. If polymerization is carried out close to either boundary of the nematic phase, the process triggers the transition into the adjacent phase, to higher or to lower degree of order.
منابع مشابه
Tuning the defect configurations in nematic and smectic liquid crystalline shells.
Thin liquid crystalline shells surrounding and surrounded by aqueous phases can be conveniently produced using a nested capillary microfluidic system, as was first demonstrated by Fernandez-Nieves et al. in 2007. By choosing particular combinations of stabilizers in the internal and external phases, different types of alignment, uniform or hybrid, can be ensured within the shell. Here, we inves...
متن کاملMorphogenesis of liquid crystal topological defects during the nematic-smectic A phase transition
The liquid crystalline phases of matter each possess distinct types of defects that have drawn great interest in areas such as topology, self-assembly and material micropatterning. However, relatively little is known about how defects in one liquid crystalline phase arise from defects or deformations in another phase upon crossing a phase transition. Here, we directly examine defects in the in ...
متن کاملNMR measurement of smectic ordering and nematic–smectic-A coupling in a liquid crystal
The nuclear magnetic resonance (NMR) spectra of three substituted benzenes as solutes in the liquid crystal 8CBwere investigated. The orientational order of all solutes was obtained in the nematic and smectic-A phases. A change in temperature dependence of orientational ordering was observed at the nematic to smectic-A phase transition. We analyzed these results via Kobayashi–McMillan theory ap...
متن کاملCrystal-liquid crystal binary phase diagrams.
We propose a new theoretical scheme for the binary phase diagrams of crystal-liquid crystal mixtures by a combination of a phase field model of solidification, the Flory-Huggins theory for liquid-liquid mixing and Maier-Saupe-McMillan (FH-MSM) model for nematic and smectic liquid crystal orderings. The phase field theory describes the crystal phase transition of anisotropic organic crystal and/...
متن کاملExistence of Solutions to Boundary Value Problems for Smectic Liquid Crystals
We prove lower semicontinuity and lower bounds for a Chen-Lubensky energy describing nematic/smectic liquid crystals with physically realistic boundary conditions. The Chen-Lubensky energy captures stable phases of the liquid crystal material, ranging from purely nematic or smectic states to coexisting nematic/smectic states. By including appropriate additional terms, the model includes the eff...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Advanced materials
دوره 28 46 شماره
صفحات -
تاریخ انتشار 2016